Compounds of Arsenic, Antimony, and Bismuth: Covering the by Michael Dub (auth.), Michael Dub (eds.)
By Michael Dub (auth.), Michael Dub (eds.)
The target of this compilation has been to supply a accomplished, non-criti cal resource of knowledge touching on organometallic compounds. The scope is restricted to the compounds containing a minimum of one carbon-metal bond. The in formation contains tools of practise, houses, chemical reactions, and purposes. the 1st version comprised the literature from 1937 to 1958. the second one variation is totally revised and prolonged via 1964. The literature ahead of 1937 used to be completely coated by way of E. Krause and A. von Grosse in I~ie Chemie der meta11-organischen Verbindungen, " Verlag von Gebrueder Borntraeger, Berlin, 1937. Our paintings comprises 3 volumes. quantity I includes derivatives of the transition metals of teams III via VIII of the Periodic desk. quantity II comprises derivatives of germanium, tin, and lead. quantity III comprises derivatives of arsenic, antimony, and bismuth. The compilation relies on searches via Chemical Abstracts. The col lection of references for 1964 used to be accomplished earlier than the topic Indexes to Volumes 60 and sixty one of the Abstracts have been to be had; hence a few omissions within the assurance of that 12 months are attainable. we have now tried to make the insurance of the literature whole so that the compilation could have most sensible software to the chemist, chemical engineer, patent lawyer, and editor. within the curiosity of brevity, yes numerical information are passed over, yet references to the unique literature are given. Yield info are rounded to 2 major figures. anywhere attainable, tables were used. The entries within the Bibliography part contain references to Chemical Abstracts.
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Additional info for Compounds of Arsenic, Antimony, and Bismuth: Covering the Literature from 1937 to 1964
Hg(AsPrs)121e, white needles, m. 107-108°, prepd. from PrsAs + Hgl2 (1:1) in warm ale. or in aq. ; crystallographic data; an I-bridged structure postulated (352). [(PrsAs)s(HgI2)2J, pale yellow leaflets, m. 5°, prepd. by shaking a 12 soln. of HgI2 in aq. KI with excess PrsAs; the structure suggested (352). PrsAs [(PrsAs)2(HgC12)S], colorless, monoclinic crystals, m. 105°, prepd. from PrsAs and HgC12 (1:3) in aq. ; crystallographic dataj the Cl Cl /Cl /AsPrs structure suggested (352). 'Hg'" ~Hg ~gl(' prsAs/ 1',,,1/ .........
O, [Pt(AsBus)C12]e, orange crystals, m. 126-127°, prepd. by treating molten cisand/or trans-[Pt(AsBus)~12J with PtC12; a Cl-bridged structure suggested (207). [Rh(BuSAs)SClS], red prisms, m. ), prepd. by boiling RhCls·~~O with BusAs in EtOH; a trans configuration postulated (2l67). Uses: A catalyst for the condensation of silanes with unsatd. nitriles (1~94). A complex formed with Ti halides and organoaluminums catalyzed a stereospecific polymerization of olefins (1594). : from As 2 0S by heating with (Me~HC~)sAl in CeH~4 at 60°, ~2% yield along with [(Me2CHC~)2As leo (2110, 2111).
From [Hg(AsEt3)I2k by heating with F3C1 at 100° (1600). From Et3As by heating with CF31 at 100° (1728, 2084). By-prod. from the rxn. of Et2AsI with CF31 in the presence of Hg at 20° (1728). : b. 110-114° (1728); b. 1110 (1727), b. 1100 (2084). IR spectrum (1727, 2084). Rxn. with: EtI at 150° ~ CF3H, C2H4, CF3I, and Et4AsI3 (1728). Liq. NH3 at 20° ~ CHF3 (7%) (1729). 10% NaOH at 100° ~ CHF3 (34%) (1729). 20% NaOH at 200 ~ CHF3 (1%) (1729). : from MeAsI2 by treating with EtMgBr in Et20 (1988). Rxn.