Drama

Drama in Dynamics : Boom, Splash, and Speed by Heather Marie Netzloff; Ames Laboratory.; United States.

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By Heather Marie Netzloff; Ames Laboratory.; United States. Dept. of Energy. Office of Science.; United States. Dept. of Energy. Office of Scientific and Technical Information

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Sample text

J. Phys. Chenz. 1992,96, 1173. R. Znorg. Chent. 1996,35,7124. J. Chem. un&n 2000,4, 140. (6) Curtius, T. Ber. Dtsch. Chenz. Ges. 1890,23,3023. ; Runeberg, N. J. Mol. Sfruct. ) 1991, 234,279. (8) (a) Christe, K. ;Guertin, J. ; Pavlath, A. E. Inorg. NucE. Chem. Lett. 1966,2,83; (b) Guertin, J. ; Christe, K. ; Pavlath, A. E. Inorg. Chenz. 1966, 5, 1921; (c) Tolberg, W. ; Rewick, R. ; Stringham, R. S. hnorg. Chem. 1967,6, 1 1 5 6 . (9) (a) Christe, K. 0. Znorg. Nucl. Chem. Lett, 1972,8, 741; (b) Robero, F.

It is important to reiterate here the following point: the reason that the amount of energy required to cause dissociation in the DRP trajectories exceeds the calculated barrier heights is that the energy provided to a specific vibrational mode does not localize in the bond that breaks in the reaction. Experimental Results. The vacuum thermolyses of N,’AsF; [N,Jt2[SnFJ” (eq. 6), and the displacement reaction between CsF and N,’SbF; (eq. 5) and (eq. 7) were studied experimentally by fast, in situ FT-IR spectroscopy of the gaseous reaction products.

Un&n 2000,4, 140. (6) Curtius, T. Ber. Dtsch. Chenz. Ges. 1890,23,3023. ; Runeberg, N. J. Mol. Sfruct. ) 1991, 234,279. (8) (a) Christe, K. ;Guertin, J. ; Pavlath, A. E. Inorg. NucE. Chem. Lett. 1966,2,83; (b) Guertin, J. ; Christe, K. ; Pavlath, A. E. Inorg. Chenz. 1966, 5, 1921; (c) Tolberg, W. ; Rewick, R. ; Stringham, R. S. hnorg. Chem. 1967,6, 1 1 5 6 . (9) (a) Christe, K. 0. Znorg. Nucl. Chem. Lett, 1972,8, 741; (b) Robero, F. Q. Inorg. Nucl. Cham. 1972, 8,737; (c) Chiiste, K. Inorg. Chenz.

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